A shallow vertical CO2 injection test was conducted over a 21 day period at the Ginninderra Controlled Release Facility in May 2011. The objective of this test was to determine the extent of lateral CO2 dispersion, breakthrough times and permeability of the soil present at the Ginninderra site. The facility is located in Canberra on the CSIRO agricultural Ginninderra Experiment Station. A 2.15m deep, 15cm stainless steel screened, soil gas sampling well was installed at the site and this was used as the CO2 injection well. The CO2 flow rate was 1.6 L/min (STP). CO2 soil effluxes (respiration and seepage) were measured continuously using a LICOR LI-8100A Automated Soil CO2 Flux System equipped with 5 accumulation chambers spaced 1m apart in a radial pattern from the injection well. These measurements were supplemented with CO2 flux spot measurements using a WestSystems portable fluxmeter. Breakthrough at 1m from the injection point occurred within 6 hrs of injection, 32hrs at 2m and after almost 5 days at 3m. The average steady state CO2 efflux was 85 ?mol/m2/s at 1m, 15 ?mol/m2/s at 2m and 5.0 ?mol/m2/s at 3m. The average background CO2 soil respiration efflux was 1.1 - 0.6 ?mol/m2/s. Under windy conditions, higher soil CO2 efflux could be expected due to pressure pumping but this is contrary to the observed results. Prolonged windy periods led to a reduction in the CO2 efflux, up to 30% lower than the typical steady state value.

In this paper, we present a high resolution study focussed mainly on the Gorgon field and associated Rankin Trend gas fields, Carnarvon Basin, Australia (Figure 1). These gas fields are characterized by numerous stacked reservoirs with varying CO2 contents and provide a relevant natural laboratory for characterizing CO2 migration, dissolution and reaction by looking at chemical characteristics of the different reservoirs (Figure 2). The data we present reveal interesting trends for CO2 mol% and -13C both spatially and with each other as observed by Edwards et al. (2007). Our interpretation of the data suggests that mineral carbonation in certain fields can be significant and relatively rapid. The Gorgon and Rankin Trend fields natural gases may therefore be a unique natural laboratory, which give further insights into the rates and extent of carbonate mineral sequestration as applied to carbon storage operations.

Geoscience Australia and the CO2CRC have constructed a greenhouse gas controlled release facility at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The facility is designed to simulate surface emissions of CO2 (and other greenhouse gases) from the soil into the atmosphere. CO2 is injected into the soil is via a 120m long slotted HDPE pipe installed horizontally 2m underground. This is fitted with a straddle packer system to partition the well into six CO2 injection chambers with each chamber connected to its own CO2 injection line. CO2 was injected into 5 of the chambers during the first sub-surface release experiment (March - May 2012) and the total daily injection rate was 100 kg/d. A krypton tracer was injected into one of the 5 chambers at a rate of 10 mL/min. Monitoring methods trialled at the site include eddy covariance, atmospheric tomography using a wireless networked array of solar powered CO2 stations, soil flux, soil gas, frequency-domain electromagnetics (FDEM), soil community DNA analysis, and krypton tracer studies (soil gas and air). A summary of the findings will be presented. Paper presented at the 2012 CO2CRC Research Symposium, Sunshine Beach, 27-29 November 2012.

Geoscience Australia and the CO2CRC operate a controlled release facility in Canberra, Australia, designed for simulating subsurface emissions of CO2 by injecting gas into a horizontal well. Three controlled release experiments were conducted at this site during 2012-2013, over 7-9 week periods, to assess and develop near-surface monitoring technologies for application to carbon dioxide geological storage sites (Feitz et al., 2014). A key well-established technique for characterizing surface CO2 emission sources from controlled release sites or natural CO2 seeps is soil flux surveys. The technique is often considered as the benchmark technique for characterizing a site's emissions or as a baseline for comparing other measurement techniques, but has received less attention with regards to its absolute performance. The extensive soil gas surveys undertaken during Release 1 (Feb-May 2012) and Release 3 (Oct-Dec 2013) are the subject of this paper. Several studies have highlighted factors which can have an effect on soil flux measurements, including meteorological influences such as air pressure and wind speed, which can increase or suppress soil fluxes (Rinaldi et al. 2012). Work at the Canberra controlled release site has highlighted the influence groundwater has on the spatial distribution of fluxes.). In addition, there are several different methods available for inverting soil flux measurements to obtain the emission rate of a surveyed area. These range in complexity from planar averaging to geostatistical methods such as sequential Gaussian simulation (Lewicki et al. 2005). Each inversion technique relies on its own subset of assumptions or limitations, which can also impact the end emissions estimate. Thus deriving a realistic estimate of the total emission rate will depend on both environmental forcing as well as the applied inversion method. An in-house method for soil flux interpolation has been developed and is presented. A cubic interpolated surface is generated from all the measurement points (Figure 1), from which a background linear interpolated surface is subtracted off, leaving the net leakage flux. The background surface is prepared by identifying all background points matching a certain criteria (for this release experiment distance from release well was used) and interpolating only over those points. In these experiments, soil flux surveys were collected on a predefined grid, using an irregular sampling pattern with higher density of samples nearer to the leak hotspots to provide higher spatial resolution in the regions where flux changes most rapidly (Figure 2). The same release rate of 144 kgCO2/day was used for both experiments. It was observed that the surface flux distribution shifts markedly between experiments, most likely a function of seasonal differences (2012 was wet; 2013 was dry) and resulting differences in groundwater depth, soil saturation and the extent of the vadose zone.. The depth to the groundwater measured at monitoring wells in proximity to the release well was 0.85-1.2 m during the 2012 (wet) release whereas it ranged from 1.9-2.3 m during the 2013 (dry) release experiment. The horizontal well is located 2.0 m below the ground surface. This paper explores the performance of soil flux surveys for providing an accurate estimate of the release rate, using a series of soil flux surveys collected across both release experiments. Emission estimates are generated by applying several common inversion methods, which are then compared to the known release rate of CO2. An evaluation as to the relative suitability of different inversion methods will be provided based on their performance. Deviations from the measured release rate are also explored with respect to survey design, meteorological and groundwater factors, which can lead and inform the future deployment of soil flux surveys in a monitoring and verification program.

High-CO2 gas fields serve as important analogues for understanding various processes related to CO2 injection and storage. The chemical signatures, both within the fluids and the solid phases, are especially useful for elucidating preferred gas migration pathways and also for assessing the relative importance of mineral dissolution and/or solution trapping efficiency. In this paper, we present a high resolution study focused on the Gorgon gas field and associated Rankin trend gases on Australia's Northwest Shelf of Australia. The gas data we present here display correlate-able trends for mole %-CO2 and %- C CO2 both areally and vertically. Generally, CO2 mol % decreases and becomes depleted in %- C (lighter) upsection and towards the north; a trend which also holds true for the greater Rankin trend gases in general. The strong spatial variation of CO2 content and %- C and the interrelationship between the two suggests that processes were active to alter the two in tandem. We propose that these variations were driven by the precipitation of a carbonate phase, namely siderite, which is observed as a common late stage mineral. This conclusion is based on Rayleigh distillation modeling together with bulk rock isotopic analyses of core, which confirms that CO2 in gases are genetically related to the late stage carbonate cements. The results from this study have important implications for carbon storage operations and suggest that significant CO2 may be reacted out a gas plume over short migration distances.

Atmospheric tomography is a monitoring technique that uses an array of sampling sites and a Bayesian inversion technique to simultaneously solve for the location and magnitude of a gaseous emission. Application of the technique to date has relied on air samples being pumped over short distances to a high precision FTIR Spectrometer, which is impractical at larger scales. We have deployed a network of cheaper, less precise sensors during three recent large scale controlled CO2 release experiments; one at the CO2CRC Ginninderra site, one at the CO2CRC Otway Site and another at the Australian Grains Free Air CO2 Enrichment (AGFACE) facility in Horsham, Victoria. The purpose of these deployments was to assess whether an array of independently powered, less precise, less accurate sensors could collect data of sufficient quality to enable application of the atmospheric tomography technique. With careful data manipulation a signal suitable for an inversion study can be seen. A signal processing workflow based on results obtained from the atmospheric array deployed at the CO2CRC Otway experiment is presented.

Abstract for submission to 11th IEA GHG International Conference on Greenhouse Gas Control Technologies. Conference paper to follow pending selection for oral or poster presentation. Abstract covers the GA-ACCA21 China Australia Geological Storage of CO2 (CAGS) Project run through PMD/ED 2009-2012.

In mid 2011, the Australian Government announced funding of a new four year National CO2 Infrastructure Plan (NCIP) to accelerate the identification and development of sites suitable for the long term storage of CO2 in Australia that are within reasonable distances of major energy and industrial CO2 emission sources. The NCIP program promotes pre-competitive storage exploration and provides a basis for the development of transport and storage infrastructure. The Plan follows on from recommendations of the Carbon Storage Taskforce and the National CCS Council (formerly, the National Low Emissions Coal Council). It builds on the work funded under the National Low Emissions Coal Initiative and the need for adequate storage to be identified as a national priority. Geoscience Australia is providing strategic advice in delivering the plan and will lead in the acquisition of pre-competitive data and geological studies to assess storage potential. Four offshore sedimentary basins (Bonaparte, Browse, Perth and Gippsland basins) and several onshore basins have been identified for pre-competitive data acquisition and study.

Quantification of leakage into the atmosphere from geologically stored CO2 is achievable by means of atmospheric monitoring techniques if the position of the leak can be located and the perturbation above the background concentration is sufficiently large for discrimination. Geoscience Australia and the CO2CRC have recently constructed a site in northern Canberra for the controlled release of greenhouse gases. This facility enables the simulation of leak events and provides an opportunity to investigate techniques for the detection and quantification of emissions of CO2 (and other greenhouse gases) into the atmosphere under controlled conditions. The facility is modelled on the ZERT controlled release facility in Montana. The first phase of the installation is complete and has supported an above ground, point source, release experiment (e.g. simulating leakage from a compromised well). Phase 2 involves the installation of a shallow underground horizontal well for line source CO2 release experiments and this will be installed during the first half of 2011. A release experiment was conducted at the site to explore the application of a technique, termed atmospheric tomography, to simultaneously determine the location and emission rate of a leak when both are unknown. The technique was applied to the release of two gas species, N2O and CO2, with continuous sampling of atmospheric trace gas concentrations from 8 locations 20m distant from a central release point and measurement of atmospheric turbulence and dispersive conditions. The release rate was 1.10 ± 0.02 g min-1 for N2O and 58.5 ± 0.4 g min-1 for CO2 (equivalent to 30.7 ± 0.2 tonnes CO2 yr-1). Localisation using both release species occurred within 0.5 m (2% error) of the known location. Determination of emission rate was possible to within 7% for CO2 and 5% for N2O.

Groundwater has been sampled from 21 shallow (Port Campbell Limestone) and 3 deep (Dilwyn Formation) groundwater bores within a radius of 10 km around well CRC-1 between June 2006 and March 2008. The objectives of the study are (1) to establish baseline aquifer conditions prior to CO2 injection at CRC-1, which started in April 2008, and (2) to enable detection monitoring for CO2 leakage, should any occur in the future. In addition to sampling, standing water levels have been monitored continuously in 6 of the bores using barometric loggers. The water samples were analysed for pH, electrical conductivity (EC), temperature (T), dissolved oxygen (DO), redox potential (Eh), reduced iron (Fe2+) and alkalinity (dissolved inorganic carbon, DIC, as HCO3-) in the field, and for a suite of major, minor and trace inorganic species in the laboratory. Stable isotopes of O and H in water, of S in sulfate and of C and O in DIC were also determined. The shallow groundwaters have compositions typical of carbonate aquifer hosted waters, being fresh (EC 800-4000 uS/cm), dominated by Ca, Na, HCO3- and Cl-, cool (T 12-23°C), and near-neutral (pH 6.6-7.5). Most deep groundwater samples are similarly fresh or fresher (EC 400-1600 uS/cm), also dominated by Ca, Na, HCO3- and Cl-, cool (T 15-21°C), but are more alkaline (pH 7.5-9.5). Time-series reveal that parameters measured have been relatively stable over the sampling period, although some shallow bores display increasing EC and T, some show decreasing then increasing alkalinity while others show steadily increasing alkalinity (with or without increasing Cl- and Na, and decreasing Ca). Alkalinity of the deep groundwater tends to decrease slightly over the period. Groundwater levels in some of the shallow bores show a seasonal variation with longer term trends evident in both aquifers.